Scientists at the U.S. Department of Energy’s (DOE) Institute for Cooperative Upcycling of Plastics (iCOUP) have developed a new method for recycling HDPE. Using a novel catalytic approach, iCOUP scientists from DOE’s Argonne National Laboratory and Cornell University transformed waste HDPEplastic into a new material that can be recycled repeatedly without loss of quality. “Plastics are going to be with us forever. They provide functionality that no other material can provide. We need to find ways to reduce the harmful effects of plastic use by improving recyclability,” said Argonne’s Massimiliano Delferro, a scientist on the study.
The team’s new approach converts used HDPE into a fully recyclable and potentially biodegradable material with the same mechanical and thermal properties of the starting single-use plastic. If adopted widely, approaches like this could eventually help to reduce the carbon emission and pollution associated with HDPE. “We are using waste plastic as our source instead of fossil fuels,” said Cornell’s Geoffrey Coates, a scientist on the study. “Instead of drilling for oil and polluting the environment, we’re using stuff that would otherwise be incinerated or left in a landfill.”
Like other plastics, HDPE is comprised of long chains of atoms called polymer chains. The team’s new approach uses a series of catalysts — or chemicals that accelerate chemical reactions — to break the HDPE polymer chains into shorter pieces that contain reactive groups of atoms at the ends. Those pieces can then be put back together, or repolymerized, to form new plastic products. The reactive end groups have the added benefit of making the new plastic easier to decompose, both in the lab and potentially in nature.
The Argonne team performed the first round of catalysis on used HDPE products, including water jugs and packaging. The catalysts choose at random which spots to alter in the polymer chains to make them reactive. The longer the scientists leave the HDPE with the catalyst, the more the chains are activated.
Then, the Cornell team took these activated polymer chains and exposed them to another catalyst. At this stage, the catalyst breaks up the chains and further alters the ends to enable reassembly. The main challenge was to reproduce the same material properties of HDPE — such as strength and flexibility versus brittleness — in the new material. When the catalysts break up the HDPE, it’s important that there remain enough long polymer chains to bind to each other like threads, making the material more resilient to stress.
When the Cornell team originally repolymerized the catalyzed material, it was much more brittle than the starting HDPE. They then fine-tuned the catalysts to break up the polymer chains in a way that provides a controlled amount of branching when the material is repolymerized. This branching allows chains to form off of the end groups, thereby increasing the average length of the chains in the resulting material. This approach resulted in a material with the same properties as the starting HDPEand greater recyclability.
Future work will focus on assessing the biodegradability of the new material and reducing the amount of valuable metal used for the catalyst to reduce the overall recycling cost. The team also hopes to apply their strategy to other common plastics.